Symmetry breakings in a metal organic framework with a confined guest
نویسندگان
چکیده
منابع مشابه
Selective guest docking in metal-organic framework materials.
The 1990s saw a quest towards synthesizing modular porous materials from metal-containing linker groups and organic molecule struts. The idea, perhaps in analogy to the spools and sticks of the popular “Tinkertoy” sets, was to use molecular linkers with multiple chelating sites and molecular struts of different lengths to generate porous solid materials with custom-designed pore sizes and shape...
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Photocatalytic degradation of toxic organic compound in water, soil and air by semiconductor catalysts such as TiO2 and ZnO have received much attention over the last two decades. However, the low quantum yield, easy agglomeration and difficult post-separation of these inorganic catalysts limit their application for large-scale applications. Metal-organic frameworks (MOFs) are the latest class ...
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A major goal of heterogeneous catalysis is to optimize catalytic selectivity. Selectivity is often limited by the fact that most heterogeneous catalysts possess sites with a range of reactivities, resulting in the formation of unwanted by-products. The construction of surface-confined covalent organic frameworks (sCOFs) on catalytically active surfaces is a desirable strategy, as pores can be t...
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ژورنال
عنوان ژورنال: Physical Review B
سال: 2020
ISSN: 2469-9950,2469-9969
DOI: 10.1103/physrevb.101.134103